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Corrosion: Understand It to Fight It

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Knowing what your operations are up against is crucial in preventing costly, potentially dangerous, damage.

CORROSION COSTS

There have been many studies about the cost of corrosion.

NACE International, formerly known as the National Association of Corrosion Engineers (nace.org, Houston), conducted research from 1999 to 2001 that found direct corrosion costs in the United States amounted to $276 million (about 3.2% of the country’s GDP). In March 2016, NACE released a study that estimated worldwide corrosion amounted to $2.5 trillion (about 3.4% of the GDP) and indirect costs doubled that.

In the 2016 study, NACE estimated that between 15% and 35% of those corrosion-related costs could be eliminated using current technology. Researchers also offered that, comparing corrosion costs in 1975 with those in 1999, an intelligent approach to automobile design and elimination of corrosion appeared to have reduced the cost to American consumers by about 52%.

HOW CORROSION OCCURS

Energy is needed to convert mined ores into useful metals. Corrosion is the natural result of those metals trying to revert back to their original states. Consider, for example, that there’s very little difference between the rust from corroded steel and the iron ores that were originally refined to make that steel.

Fig. 1 Depicting a steel bar in liquid, this diagram shows how corrosion occurs. The liquid contains water. When iron ions (Fe) off the bar unite with oxygen in the water, different kinds of rust can form.

Fig. 1 Depicting a steel bar in liquid, this diagram shows how corrosion occurs. The liquid contains water. When iron ions (Fe) off the bar unite with oxygen in the water, different kinds of rust can form.

he actual corrosion process is an electrochemical reaction. Depicting a steel bar in a liquid, Fig. 2, shows how this reaction takes place. In the diagram, corrosion is attacking the anode, with iron ions being released into the solution, while hydrogen is being generated at the cathode. Water (H2O), is made up of two hydrogen ions and one oxygen ion. The iron ions from the anode (the Fe symbols) will ultimately unite with oxygen in the water, whereupon several different types of rust can form.

At the cathode site of the piece, atomic hydrogen is being released. Most of those hydrogen ions then mate with another hydrogen ion and form molecular hydrogen, the readily flammable gas we’re used to thinking about. But some of the ions remain solitary and they are the cause of the many forms of hydrogen damage including hydrogen embrittlement, cracking, and blisters.

For wet corrosion, a liquid must be present to provide the complete circuit required by the electromechanical reaction. Electrons that flow from the cathode to the anode have to eventually return to the cathode, and they do so by traveling through the liquid.

Chemicals such as road salt are in the silt. As the moisture in it evaporates, the chemical concentration increases. The chemicals, in turn, make the water more electrically conductive and significantly increase the rate of corrosion.   

Temperature is a third important factor in corrosion. Below freezing, ice can’t conduct corrosion currents. But, as the temperature increases, the corrosion rate increases. A good example is the rapid attack on hot piping with moist insulation. The exact solution chemistry has a major effect, but up to about 175 F (80 C), the corrosion rate usually rapidly increases, then drops off and ceases when the liquid vaporizes.

TYPES OF CORROSION

Uniform corrosion causes about 80% of all corrosion. It occurs where anode and cathode sites relatively uniformly swap position. Examples include the railroad-bridge-support column shown in Fig. 1, buried steel water lines, nooks and crannies on vehicles where deposits build up, and machine frames and bases in damp areas.

Pitting corrosion manifests as isolated areas of attack. With carbon steel, it may take years before leakage occurs while stainless-steel pitting might progress at a rate of 0.001 in. (0.025 mm)/day. Steel examples frequently include water and wastewater tanks. Stainless-steel examples include external areas with dirt deposits on them.    

Galvanic corrosion occurs when two chemically different metals are joined. One is always the anode and continuously attacked, protecting the other piece. A common example involves a joint between steel and copper pipe, where the steel will always be attacked. 

Fig 2. A common example of galvanic corrosion involves a joint between steel and copper pipe where the steel will always be attacked. This joint was submerged in water for only nine months before damage occurred.

Fig 2. A common example of galvanic corrosion involves a joint between steel and copper pipe where the steel will always be attacked. This joint was submerged in water for only nine months before damage occurred.

Figure 3 shows a bronze fitting and a steel pipe that had been submerged in water. Perforation of the freshly cut pipe threads happened in only nine months.

Selective leaching is essentially galvanic corrosion within a metal. The common industrial application involves buried cast-iron water or waste lines where the graphite in the iron acts as a cathode, and the iron is eaten away, leaving a weak and brittle graphite pipe. When initially excavated, the pipe may appear almost undamaged, but sandblasting will rapidly remove the graphite leaving proof of the mechanism. (A frequent problem with buried-pipe replacement is that the new piece is always anodic to the older sections. The new one will rapidly corrode and leak, and personnel will blame the material, not knowing that the actual problem is their lack of corrosion knowledge.)

Crevice corrosion occurs in a small gap between two pieces of metal. It allows a corrosion mechanism to act in a way that’s similar to pitting corrosion. Although it’s not a common industrial mechanism, it can happen with poor joint control on welded assemblies.

Intergranular corrosion involves galvanic attack at the grain boundaries within a   metal. It’s usually associated with a poor choice in materials of construction for  chemical processes.

Erosion corrosion is a combination of actions. Corrosion results in an oxide on a metal’s surface. The oxide, though, slows the attack because it prevents fresh corrodent from reaching the surface. If there’s a fast fluid flow that scrubs the oxide off the surface, corrosion continues at a very rapid rate. A common site for erosion corrosion is the outer radius of piping elbows in steel lines with untreated waters and flow rates exceeding approximately 10 ft./sec. (3 m/sec). It’s also been seen in pumps as a result of poor choices of construction materials.

The previous seven categories/types are basically different-looking versions of galvanic corrosion. Two other corrosion types—stress-corrosion cracking and hydrogen damage—result in metallurgical damage leading to often hard-to-detect catastrophic failures.

Stress corrosion cracking (SCC) can occur with almost any metal and is the result of a combination of stress, a chemistry that attacks the metal’s structure, and a susceptible metal. Industrially, although it is sometimes seen with nitrates and steel, the most common situation involves 300 series (austenitic) stainless steels and chlorides.

KEEP IN MIND

The battle against corrosion is never ending. In summary, if an area is wet and metal isn’t protected, there will be corrosion. What’s worse, the seriousness of the damage caused by this scourge may not be recognized for years. 

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THE BEAUTY OF MONOLITHIC INSULATING JOINTS

Much of the world runs on pipelines. When you drive your car, the fuel that you use will probably have passed under pressure through pipelines at some stage. The water that you drink, likewise, just like the gas that you use to heat your dinner. And these pipelines depend on monolithic insulating joints.

This is because pipelines are subject to corrosion, just like any metal object that is exposed to the elements. Whether overground, underwater or buried underground, pipelines need to be protected against damage from water and the air, as well as electric currents generated by lightning.

Simpler, easier to use and more effective than older anti-corrosion methods

Monolithic insulating joints (or isolation joints) provide just such protection. Specially designed to be shock absorbent and insulated against the electrical charge, they isolate sections of the pipeline so that currents can only pass so far. Materials placed within the monolithic isolation joint also work by attracting electrical charge and preventing corrosion. This is achieved by something called cathode protection - where the material in the joint becomes an anode, and the pipeline becomes a cathode. The anode protects the pipeline from corrosion. You can see the same devices attached to ships, while they are also installed in concrete constructions and on bridges as well. Without them, complex engineering would be extremely difficult.

The advantages of using the monolithic isolation joint are that this kind of joint avoids small parts such as gaskets and flanges, and can be produced to exacting standards of precision. They can be ordered in whatever pipe size is required and sealed easily and safely without the need for welding. They can also be delivered to clients pre-tested and produced to the specifications of the client, avoiding the need for technicians to attend to the installation process.

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Save money and prevent accidents by using the latest technology

Every monolithic insulating joint can be fully customized for the needs of each client. They are adapted for both main and service line applications and come in a wide range of different diameters.

By installing a monolithic insulating joint at periodic points along the pipeline, firms can prevent leakages in pipelines carrying liquids such as water, liquid gas and petroleum, and also stop electric currents passing through the pipe casing, improving safety. They are a cheap, effective solution to the problems faced by pipeline maintenance operations across the world.

Previously, oil and gas firms have often relied on less effective and more expensive insulating flange kits. With the need to avoid industrial accidents and financial losses through leakage greater than ever, it makes sense to invest in the most efficient way to safeguard pipelines against corrosion. That is why European and Middle Eastern firms have already embraced isolation joints, and why American operators are following suit.

Ref: http://www.meccanicasegrino.com/the-beauty-of-monolithic-insulating-joints.aspx

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